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Notes: Reactivity of Aryl Isocyanates

✍ Scribed by Brock, F

Book ID: 119958240
Publisher: American Chemical Society
Year: 1959
Tongue: English
Weight: 310 KB
Volume: 24
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo01093a615

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## Abstract Reaction of chloroglyoxime 1 with aryl isocyanates yielded monocarbamates 3, and chlorooxime functional group was unchanged. The 1,3‐cycloaddition of nitrile N‐oxides generated from 3 to methyl methacrylate gave isoxazole derivatives 5. Compounds 5 were also obtained by carbamoylation o