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Notes on the synthesis of meso-substituted porphyrins from pyrryl carbinols and the mechanism of the rothemund reaction

โœ Scribed by Robert G. Little


Book ID
112126461
Publisher
Journal of Heterocyclic Chemistry
Year
1981
Tongue
English
Weight
183 KB
Volume
18
Category
Article
ISSN
0022-152X

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The aerobic oxidation process for the synthesis of porphyrins, previously performed using 5 mol % p-chloranil (TCQ), 5 mol % iron(II) phthalocyanine (FePc) and stoichiometric amounts of O 2 , has been refined using new phthalocyanine catalysts. Four phthalocyanine catalysts have been prepared, chara