Notes - Cyclic Peroxide By-Product from the Alkaline Epoxidation of Mesityl Oxide
β Scribed by Payne, George
- Book ID
- 126141002
- Publisher
- American Chemical Society
- Year
- 1958
- Tongue
- English
- Weight
- 255 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
## Abstract It was found that __tert__βBuNH~2~ is an efficient catalyst for epoxidation of __Ξ±__,__Ξ²__βunsaturated ketones with 30% H~2~O~2~ under mild conditions. For most of the cyclic unsaturated ketones used, moderate to excellent yields (45%β93%) were obtained within 24 h period.
Solid and liquid carbonaceous by-products have been obtained in both coal gasification and liquefaction processes. A study of the oxidation of the solid by-products was undertaken to determine what commercial chemicals could be derived from these materials. The oxygen oxidation of various coal-conve