oxocarboxylic acids and esters oxocarboxylic acids and esters (acyclic compounds)
Note on the Reaction of Aminoacetonitrile Hydrochloride with Trimethyl Orthoformate
✍ Scribed by Winkler, Tammo ;Lutz, William ;Kristinsson, Haukur
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 100 KB
- Volume
- 1985
- Category
- Article
- ISSN
- 0947-3440
No coin nor oath required. For personal study only.
✦ Synopsis
Notiz über die Reaktion von Aminoacetonitril‐hydrochlorid mit Orthoameisensäure‐trimethylester
Aminoacetonitril‐hydrochlorid (1) liefert mit Orthoameisensäure‐trimethylester (2) N‐Formyl‐aminoacetonitril (5) und nicht – wie berichtet – das 5(4__H__)‐Imidazolon (3). Als Zwischenprodukt dieser Reaktion entsteht N‐(Cyanmethyl)formimidsäure‐methylester (4).
📜 SIMILAR VOLUMES
## Abstract 3‐Acetyltropolone (1) reacted with benzaldehydes in trimethyl orthoformate in the presence of perchloric acid to afford 2‐aryl‐4‐methoxy‐9‐oxocyclohepta[__b__]pyrylium perchlorates 3a‐c in 25–37% yields. From the filtrates, 3‐(3,4‐diaryl‐3‐butenoyl)tropolones 4a,b and 3‐(2‐methoxycinnam
## Abstract Relative rate coefficients for the reactions of OH with 3‐methyl‐2‐cyclohexen‐1‐one and 3,5,5‐trimethyl‐2‐cyclohexen‐1‐one have been determined at 298 K and atmospheric pressure by the relative rate technique. OH radicals were generated by the photolysis of methyl nitrite in synthetic a