Note on B. Kamieński's paper “The nature of the electric potential at the free surface of aqueous solutions”
✍ Scribed by A.N. Frumkin
- Publisher
- Elsevier Science
- Year
- 1960
- Tongue
- English
- Weight
- 348 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0013-4686
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✦ Synopsis
Ah&a&--It is shown that the assumption of Kamieriski that the water/air potential difference ends is a quantity of the order of 1 V, must be rejected, as leading to impossible values for the chemical hydration energies of univalent ions.
R&ann6-_On d6montre que l'hypoth&e de Kamienski selon laquelle la diff&cnce de potentiel eau/air xnIo serait de l'order de grandeur de 1 V doit Btre rejetee, car elle conduit g des valeurs impossibles pour les Energies d'hydratation chimiques d'ions monoralents.
📜 SIMILAR VOLUMES
Ortho isomers such as ortho-hydroxybenzoic or ortho-fluorobenzoic acids decrease the electric potential difference between air and aqueous solutions. When the acids are neutralized ions are built in and withdrawn into the aqueous phase, and the potential returns to the naturalsurface potential of wa
The zero-charge potentials of gallium in water as determined from the position of the minimum on the differential capacitance in dilute solutions and from the electrocapillary curves in the absence of anion adsorption are shown to coincide and to be -@97 to -0.98 V (nce). Evidence is presented supp