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Notable Effect of Fluoro Substituents in the Imino Group in Ring-Opening Polymerization of ε-Caprolactone by Al Complexes Containing Phenoxyimine Ligands

✍ Scribed by Iwasa, Naruhito; Katao, Shohei; Liu, Jingyu; Fujiki, Michiya; Furukawa, Yoshiro; Nomura, Kotohiro


Book ID
120978101
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
232 KB
Volume
28
Category
Article
ISSN
0276-7333

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Ring-opening polymerization of various c
✍ Naruhito Iwasa; Michiya Fujiki; Kotohiro Nomura 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 694 KB

Ring-opening polymerizations (ROPs) of various cyclic esters [-caprolactone (CL), ␦-valerolactone (VL), rac-lactide (LC)] using a series of Al complexes containing phenoxy-imine ligands of type, Me , have been explored in the presence of n BuOH. Synthesis and identification of 1g and 1h including s