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Norrish Type II Photoreactivity of β-Anisylalkanophenones and Solvent Effects on Stereoselective Yang Cyclization.

✍ Scribed by Jarugu Narasimha Moorthy; Prasenjit Mal


Book ID
101942516
Publisher
John Wiley and Sons
Year
2003
Weight
98 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Norrish Type II photoreactivity of β-ani
✍ Jarugu Narasimha Moorthy; Prasenjit Mal 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 172 KB

In contary to the general notion that b-arylpropiophenones are photostable, photolysis of b-anisylketones 1 and 2 is found to result in Norrish Type II reactions; Yang cyclization affords two cyclobutanols in moderate yields (31-43%) in a highly stereoselective manner. The solvents are found to exer