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Normal coordinate analysis and thermodynamic functions of niobium and tantalum pentahalides

โœ Scribed by S.P. So

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
638 KB
Volume
16
Category
Article
ISSN
0022-2860

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Preparation and Reactivity of Mono- and
Preparation and Reactivity of Mono- and Dinuclear Derivatives of Niobium and Tantalum Pentahalides with Alkyl Aryl Ethers
โœ Fabio Marchetti; Guido Pampaloni; Stefano Zacchini ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 243 KB

The niobium and tantalum pentahalides MX 5 (X = F, Cl) react with a series of bifunctional alkyl aryl ethers in a 2:1 ratio, resulting in formation of the dinuclear species H 4 , X = Cl, M = Ta, 4c; L = MeOC 6 H 5 , X = F, M = Nb, 4d; L = MeOC 6 H 5 , X = Cl, M = Nb, 4e] have been prepared by 1:1 m