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Normal and Inverse Primary Kinetic Deuterium Isotope Effects for C−H Bond Reductive Elimination and Oxidative Addition Reactions of Molybdenocene and Tungstenocene Complexes: Evidence for Benzene σ-Complex Intermediates

✍ Scribed by Churchill, David G.; Janak, Kevin E.; Wittenberg, Joshua S.; Parkin, Gerard


Book ID
121201100
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
486 KB
Volume
125
Category
Article
ISSN
0002-7863

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Applications of deuterium isotope effect
✍ Gerard Parkin 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 French ⚖ 594 KB

## Abstract The various types of deuterium isotope effects that are observed for reactions involving oxidative addition and reductive elimination reactions of H–H and C–H bonds with a transition metal center are reviewed. Copyright © 2007 John Wiley & Sons, Ltd.