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Nonstereospecific Diels-Alder reaction. II. Reaction of hexachlorocyclopentadiene with 1,1-disubstituted and monosubstituted ethylenes

✍ Scribed by Mark, Victor


Book ID
127147874
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
421 KB
Volume
39
Category
Article
ISSN
0022-3263

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Diels-Alder reactions of [(S)R]-(1E,3E)-
✍ M. Carmen CarreΓ±o; M. BelΓ©n Cid; JosΓ©L. GarcΓ­a Ruano; Mercedes Santos πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 327 KB

## Diels-Alder reactions of [(S)R]-(1E,3E )-l-p-tolylsulfinyl-l,3-pentadiene with 1-pyrrolidinyl-l-cyclohexene and methyl acrylate evidenced: i) low reactivity of the diene regardless of the electronic character of the dienophile (high pressures were always required); ii) a complete regio-and endo