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Nonplanar bis(1,3-dithiole) donors affording novel cation radical salts

✍ Scribed by Prof. Yoshiro Yamashita; Katsuhiko Ono; Dr. Shoji Tanaka; Dr. Kenichi Imaeda; Prof. Hiroo Inokuchi

Book ID: 101412933
Publisher: John Wiley and Sons
Year: 1994
Tongue: English
Weight: 427 KB
Volume: 6
Category: Article
ISSN: 0935-9648
DOI: 10.1002/adma.19940060408

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✦ Synopsis

A nonplanar molecule that forms stable ion radical salts is reported, demonstrating that planar molecules are not a prerequisite for the preparation of organic conductors. The results of cyclic voltammetry and X‐ray structural analysis are presented for stable single crystals of the cation radical salt of the dibenzo derivative of 4,9‐bis(1,3,‐dithio‐2‐ylidene)‐4,9‐dihydronaphtho[2,3‐c][1,2,5]thiadiazole. This is the first stable cation radical salt to have been succesfully obtained from a nonplanar molecule.

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