Nonlinear optical study of the five IPR isomers of C78 generated by capping C72 through C6

✍ Scribed by Rama K. Mishra; Ying-Ting Lin; Shyi-Long Lee

• Book ID: 101257416
• Publisher: John Wiley and Sons
• Year: 2000
• Tongue: English
• Weight: 401 KB
• Volume: 77
• Category: Article
• ISSN: 0020-7608
• DOI: 10.1002/(sici)1097-461x(2000)77:2<574::aid-qua9>3.0.co;2-9

✦ Synopsis

An excellent connection exists between pyramidalized angles ( p ) and the static third-order polarizability (γ ) for the five C 78 isolated pentagon rule (IPR) isomers. On the other hand, the C 72 isomers generated on the way to constructing C 78 through the circumscribe algorithm are found to have a poor correlation between γ and p . However, the change in the γ values from C 72 to C 78 could well be correlated with a more involved local parameter like the capped angles.