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Nonenzymatic browning induced by gamma60Co irradiation in model system Part 3. Spectrophotometric investigation of the carbonyl products in the system fructose/phenylalanine in aqueous solution

✍ Scribed by Zegota, A. ;Bachman, S.


Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
385 KB
Volume
28
Category
Article
ISSN
0027-769X

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✦ Synopsis


The effects of ?-irradiation on the browning reaction in the model system of fructose-phenylalanine solution were investigated. The optical absorption recorded for irradiated and heated solutions of fructose-phenylalanine was different from those of only irradiated or only heated solutions.

T o explain the role of carbonyl compounds formed during radiolysis of fructose and phenylalanine investigations of their N-methyl-benzothiazolone hydrazone hydrochloride derivatives were undertaken. It has been found that as a result of irradiation of the model system mainly aliphatic aldehydes are formed, besides a small amount of cyclic aldehydes. However during heating the contribution of aliphatic and cyclic products is similar.