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Nonempirical study on the potential energy surface of 5-methyl-1,3-dioxane

โœ Scribed by A. E. Kuramshina; S. A. Bochkor; V. V. Kuznetsov

Book ID
111464986
Publisher
SP MAIK Nauka/Interperiodica
Year
2009
Tongue
English
Weight
202 KB
Volume
45
Category
Article
ISSN
1070-4280

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The contrasting comformational behaviour
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โœ Michael J. Cook; Khalida Nasri; Sunil M. Vather ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 123 KB

tie chair + chair equilibrium of 5-aryl-5-methyl-1,3-dioxanes, unlike that of 1-aryl-I-methylcyclohexanes, is remarkably sensitive to the nature of substituents on the aromatic ring. An interaction involving the the arcmatic group and the dioxane oxygen atoms or C-O bonds is proposed.