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Noncovalent interactions in metal complexes—XI. Synthesis and stereoselectivity of 1:3 cobalt(III) complexes of 1-l-menthyloxy-3-acylacetones

✍ Scribed by S. Maeda; M. Nakamura; H. Ōkawa; S. Kida


Book ID
108428244
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
388 KB
Volume
6
Category
Article
ISSN
0277-5387

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Noncovalent interactions in metal comple
✍ Michio Nakamura; Hisashi Ōkawa; Sigeo Kida 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 358 KB

Tris-{1-I-menthyloxy3-(2-naphthoyl)acetonato}-M(II1) complexes (M = Co, Cr, Mn) were synthesized and the stereoselectivities of the complexes were examined. The complexes exhibit intense circular dichroisms in the d-d band region, demonstrating the stereoselective formation of one of the enantiomer