Nonadiabatic unimolecular reactions. 1. A statistical formulation for the rate constants
โ Scribed by Lorquet, J. C.; Leyh-Nihant, B.
- Book ID
- 119995792
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 785 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0022-3654
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
A test of the Kassel quantum expressions for unimolecular rate constants and densities of vibrational states is described. Rate constants are calculated for nine reactions previously used in such tests, over a wide range of temperatures and pressures. The Kassel expression using the geometric mean o
An electron paramagnetic resonance (EPR) technique was used to show that simple alkyl radicals readily abstract hydrogen from l,4-cyclohexadiene. Rate constants for the reaction were ca. 104-105 M-' s-' at 300 K and activation energies 5-7 kcal mol-'. For the stabilized radicals, ally1 and benzyl, t