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Nonadiabatic transitions in diatoms with one valence electron: Calculations of potential curves and differential cross sections for Li+ + Na

✍ Scribed by P. Habitz; W.H.E. Schwarz

Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 476 KB
Volume: 34
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(75)85265-1

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✦ Synopsis

Adiabatic potentia? curves and wavefunctions tie been calculated for ground and excited states of diatomic molecules formed from an alkali atom (Li, Na, K) and an alkali ion or rare gas atom (Li+, Naf, I<+, He, Ne, .&I. A model potential method has been used. The energies are believed to be reliable within a few lo-* eV. From these potentkl curves and the nonadiabatic couplicg matrix elements, elastic and inelastic differential cross sections have been obtained for the system Lii

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Nonadiabatic transitions in diatoms with one valence electron: Measurement of differential Li+Na scattering

✍ F. von Busch; J. Hormes; H.D. Liesen 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 383 KB

Experimental differential elastic cross sections for 'Li+-Na collisions (17 < Ec m < 77 eVI reflect strong rotational coupling between nuclear and electronic motion. Good agreement is found with cks'sections calculated from model potentids. Rainbow scattetilg of Na'on L.i has been observed.