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Nonadiabatic, Short-Range, Intramolecular Electron Transfer from Ruthenium(II) to Cobalt(III) Complexes †

✍ Scribed by Creutz, Carol


Book ID
120236025
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
170 KB
Volume
111
Category
Article
ISSN
0022-3654

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📜 SIMILAR VOLUMES


Intramolecular Electron Transfer from Ir
✍ Dipl.-Chem. Horst Bertram; Prof. Dr. Karl Wieghardt 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 English ⚖ 195 KB

Compound ( 1 ) (0.68g, 4mmol) is dissolved under N2 in anhydrous tetrahydrofuran (50 ml). To this solution, cooled to -113"C, is added dropwise a solution of tert-butyllithium in n-pentane (3ml,5.1 mmol; ca. 1.7 M solution). After 15min the olefin or carbonyl compound (8mmol) is addedC6]. The soluti