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Nonadiabatic Effects on Proton Transfer Rate Constants in a Nanoconfined Solvent

โœ Scribed by Ka, Being J.; Thompson, Ward H.


Book ID
127387810
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
513 KB
Volume
114
Category
Article
ISSN
0022-3654

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A dynamical theory of nonadiabatic proto
โœ Daniel C. Borgis; Sangyoub Lee; James T. Hynes ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 627 KB

A dynamical theory for the rate constant k of hydrogen atom and proton transfer reactions in solution is presented for the nonadiabatic limit, where reaction is dominated by tunneling. Coupling and splitting fluctuation effects arising from intramolecular vibrational and solvent fluctuations are inc