Nonadiabatic effects in HD+
β Scribed by Richard E. Moss; Daryl Jopling
- Book ID
- 103037862
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 289 KB
- Volume
- 260
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
For HD + a potential, that allows for the nonadiabatic effects due to its mass asymmetry, is used to study the remaining nonadiabatic effects, those common to HD Γ· and the homonuclear H~ and D~-. The analysis is in terms of effective vibrational and rotational reduced masses, together with a potential scaling factor. Isotope-independent parameters are determined.
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Nonadiabatic effects resulting from very short rise times few . Ε½ 2 . femtoseconds of intense tens of TWrcm laser pulses may enhance in an unexpected way dissociation rates of molecules interacting with such radiation fields. Starting from a given initial vibrational level, the wavepacket describin
Non-adiabatic corrections for HD+ are estimated by transforming the Hamiltonian to give an effective electrostatic potential that may be interpreted in terms of effective nuclear charges. The results compare well with previous work, particularly at large bond lengths.