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Non-trivial behavior of palladium(ii) acetate

✍ Scribed by Bakhmutov, Vladimir I.; Berry, John F.; Cotton, F. Albert; Ibragimov, Sergey; Murillo, Carlos A.

Book ID
118273190
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
188 KB
Volume
11
Category
Article
ISSN
1477-9226

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Palladium (II) - catalyzed rearrangement
Palladium (II) - catalyzed rearrangement of allylic acetates
✍ Larry E. Overman; Fredrick M. Knoll πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 French βš– 191 KB

We recently reported that mercuric trifluoroacetate was an effective catalyst for equilibrating carbamic esters of allylic alcohols at room temperature (1 8 3, X= NMe2). 394 Yields were uniformly high, and side-reactions (elimination, cyclization, &d sk2eta.l rearrangement) occasionally encountered