Non-rearrangement Reactions of the Neopentyl-Oxygen Bond. New Syntheses of Neopentyl Halides1
โ Scribed by Sommer, Leo H.; Blankman, Herbert D.; Miller, Paul C.
- Book ID
- 115449054
- Publisher
- American Chemical Society
- Year
- 1954
- Tongue
- English
- Weight
- 262 KB
- Volume
- 76
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Rate constants have been measured for the reactions of four hydrocarbon radicals with O2 in the gas phase at room temperature. Laser flash photolysis was used to generate low concentrations of radicals. A photoionization mass spectrometer followed the radical loss as a function of time. The measured
The hydrogenolysis of neopentyl iodide on reduced Co or Pt dispersed on MgO support yields increasing amounts of 2-metylbutane and 2-methylbutenes in addition to neopentane, as the temperature is raised from 50 to 150ยฐC. These results support the idea that a n-complexed half-reaction state is simult