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Non-radiative relaxation of the Eu3+ 5D1 level in NaGdTiO4

✍ Scribed by P.A.M. Berdowski; G. Blasse


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
314 KB
Volume
107
Category
Article
ISSN
0009-2614

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✦ Synopsis


Rcceivcd 5 alarch 1984 Non-radiative rchsation by multi-phonon emission has been invcstigatcd for the 5D1 level of Eu3+ in ?iaGdTiO,l. The SD,+ SDo relaxation rate has been evaluated in the temperature region between 4.2 K and room tempentUre. The temper-OtUrc dcpcndence of the relaxation rate points to a fifth-order process. The frequency of the emitted phonons corresponds with that of the Cd-O strerching vibrations.


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✍ P. Stanley May; F.S. Richardson πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 470 KB

Room-temperature lifetimes of the 'Do emission of Eu 3+ in Na3[Eu(oxydiacetate),]\*2NaCI0,+6H20 (EuODA\*H20) and Na,]Eu(oxydiacetate)s]~2NaC104~6Ds0 (EuODA.DsO) are reported. Radiative and non-radiative contributions to the total excited-state relaxation rate are determined for both compounds. It is