## Abstract **The cover picture shows** the multiple characterization methods used to unravel the electronic and geometrical structures of the unit M~A~^III^M~B~^II^, in which three oximato groups (=N−O)^−^ are present as bridging ligands. Variable‐temperature magnetic susceptibility and EPR measur
Non-Oxo Vanadium(IV) Complexes of Aminebis(phenolate) [O,N,O] Donor Ligands and Solution Studies of Isostructural VIV and MnIV Complexes
✍ Scribed by Tapan K. Paine; Thomas Weyhermüller; Eckhard Bill; Eberhard Bothe; Phalguni Chaudhuri
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 195 KB
- Volume
- 2003
- Category
- Article
- ISSN
- 1434-1948
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## Abstract Dinuclear complexes [L~2~Fe^III^~2~] (1), [L~2~Mn^III^~2~] (2a), [L~2~Mn^III^~2~(THF)~2~] (2b), [L~2~Cr^III^~2~] (3), [L(V^IV^O)~2~(OCHMe~2~)] (4) and [L~2~(V^V^O)~2~] (5) with a pentadentate phenol‐containing ligand H~3~L (= C~6~H~2~(CH~3~)(OH){[C(CH~3~)~3~]~2~(OH)NCH}~2~) bearing the
## Abstract The reactions of V^V^O(O‐__i__Pr)~3~ with [PS3′]H~3~ and [PS3]H~3~ {[PS3′]H~3~ = P(C~6~H~3~‐5‐Me‐2‐SH)~3~, [PS3]H~3~ = P(C~6~H~4~‐2‐SH)~3~} led to the formation of [V^IV^(L)] [L = P2S4′ (1a), P2S4 (1b)], where L was formed by the oxidative coupling of two PS3′ or PS3 ligands by a disulf