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Non-linear dielectric effects in solutions of o- and m-nitrotoluene in methylcyclohexane and 1,3-dimethylcyclohexane

✍ Scribed by M. Śliwińska-Bartkowiak; B. Szurkowski; T. Hilczer

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
355 KB
Volume
145
Category
Article
ISSN
0009-2614

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✦ Synopsis

The non-linear dielectric effect (NDE) was studied in solutions of c-and m-nitrotoluene in methylcyclohexane and in 1,3dimethylcyclohexane. We observed a precritical state in these solutions which was revealed by a characteristic anomalous increase in the NDE over a wide concentration range. Similar effects have been reported for solutions of o and nz-nitrotoluene in cycloalkanes and in m-nitrotoluene solutions in n-alkanes. The geometry of the solvent molecules was found to determine the concentration range within which the liquids show limited miscibility

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