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Non-Koopmans' theorem effects in the helium(I) photoelectron spectra of polyenes

✍ Scribed by Koenig, T.; Klopfenstein, C. E.; Southworth, S.; Hoobler, J. A.; Wielesek, R. A.; Balle, T.; Snell, W.; Imre, Daniel


Book ID
126091828
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
508 KB
Volume
105
Category
Article
ISSN
0002-7863

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He(I) photoelectron spectrum of BF3 has been measured with an electron energy resolution better than 15 meV. The 1A; PE band (IP,,= 15.92 eV) reveals vibrational fine structure with intervals of 0.025 eV. In the case of the 2E' PE band (IP,=20.08 eV) an additional third progression with intervals of