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Non-ideal phase behaviour of binary mixtures of triglycerides with mono- and diglycerides

โœ Scribed by M. Knoester; D.J. De Jong


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
317 KB
Volume
14
Category
Article
ISSN
0009-3084

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โœฆ Synopsis


Non-ideal miscibility in the liquid phase of mono-or diglycerides with triglycerides has been described in terms of thermodynamic excess functions. To this end the heat of mixing and the solubility temperatures of several ideal and non-ideal binary glyceride mixtures have been measured. The non-ideal phase behaviour of glyceride systems reported in the literature has been satisfactorily predicted, which indicates that the excess functions are generally applicable to mixtures of mono-or diglycerides with triglycerides.


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A computer program for non-linear least squares minimization has been applied to construct temperature-composition phase diagrams for several binary systems of different phospholipids based on their calorimetric data. The calculated phase diagram is guided to fit the calorimetric data with two adjus