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Non-heme manganese complexes of C1-symmetric N4 ligands: Synthesis, characterization and asymmetric epoxidations of α,β-enones

✍ Scribed by Bin Wang; Cheng-Xia Miao; Shou-Feng Wang; Fritz E. Kühn; Chun-Gu Xia; Wei Sun


Book ID
116680373
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
322 KB
Volume
715
Category
Article
ISSN
0022-328X

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✍ Serafino Gladiali; Fabrizia Grepioni; Serenella Medici; Antonio Zucca; Zoltán Be 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 137 KB 👁 1 views

## Abstract The enantiopure complexes **3a** and **3b** [Rh(NBD)(P,S)]^+^BF~4~^−^ [P,S = (__S__)‐2‐(diphenylphosphanyl)‐2′‐(methylthio)‐1,1′‐binaphthalene (**a**); (__S__)‐2‐(diphenylphosphanyl)‐2′‐(isopropylthio)‐1,1′‐binaphthalene (**b**)] have been prepared from [Rh(NBD)(THF)~2~]^+^BF~4~^−^ by r