200 mL) was acidified with 3 drops of 32% HCI and stirred for 15 min at 50Β°C (exclusion of light). After extraction with CH,CI,, the organic phase was dried (Na,SO,) and purified on silica gel (20 8). After removal of the solvent there remained 0.53 g (72%) of a crystalline product. For further puri
Non-Ergodic Behavior of Excited Radical Cations in the Gas Phase
β Scribed by Dipl.-Chem. Gisbert Depke; Prof. Dr. Chava Lifshitz; Prof. Dr. Helmut Schwarz; M.Sc. Eva Tzidony
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- English
- Weight
- 229 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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In the gas phase, (CH 3 ) 3 SiOSi Y (CH 3 ) 2 and (CH 3 )CH 2 SiOSi Y (CH 3 ) 2 ions 1 and 2 were formed in the external source of a Fourier transform ion cyclofrom resonance (FT-ICR) spectrometer by electron impact ionization of (CH 3 ) 3 SiOSi(CH 3 ) 3 . In the FT-ICR cell, the electrophilic cente
The gas-phase acidity of ionized benzyl alcohol and of some of its derivatives with selected reference bases has been studied by Fourier Transform Ion Cyclotron Resonance (FT-ICR) mass spectrometry. The aim was to relate the gas-phase reactivity to the behavior in aqueous solution of the radical cat