Non equivalency of oxygen nuclei in 17O−2 adsorbed on oxides

✍ Scribed by M. Che; A.J. Tench

• Publisher: Elsevier Science
• Year: 1973
• Tongue: English
• Weight: 268 KB
• Volume: 18
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(73)80417-8

✦ Synopsis

Oxy-en enriched with ' 7O has been used to investinatc the nature of oxygen species adsorbed on oxides. The z variations in the hyperfine constants of Oi, snx~ll (< 3%) for .?l_rO and ZnO, are due to different adsorption sites.

Thev become large (> 15%) for supported molybdenum due to the different spin densities on the IWO nuclei showins that 0; is probably adsorbed at an angle to the surfucc.