A range of possible techniques for assessing the "free" chloride ion content of hydrated cement pastes dosed with sodium chloride or calcium chloride have been investigated. The techniques are based on mixing powdered samples with a solvent and measuring the amount of chloride passing into solution.
Non destructive determination of the free chloride content in cement based materials
✍ Scribed by B. Elsener; L. Zimmermann; H. Böhni
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- German
- Weight
- 187 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0947-5117
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✦ Synopsis
Abstract
A non‐destructive chloride sensitive sensor element for use in cement based porous materials is presented. The sensor element determines the activity of the free chloride ions in solutions and in porous cement based materials such as cement paste, mortar or concrete. The calibration in synthetic pore solution showed a response according to Nernst law over three decades of chloride concentration. The sensor element has shown excellent reproducibility and long term stability. The sensor element has been used to monitor the chloride uptake into mortar specimens. The results show a good agreement between the free chloride content determined by the sensor and by pore water expression. Applications in monitoring of reinforced concrete structures and their limitations are discussed.
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