✦ LIBER ✦
Non-classical steady state reactions rates for the diffusion mediated reaction A + A → 0 with particle decay
✍ Scribed by Andrzej Molski
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 479 KB
- Volume
- 178
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The effective steady state rate constants for the bimolecular annihilation At A-t0 accompanied by unimolecular decay, A+O, and particle generation, S-A, are calculated in spatial dimensions d= 1, 2, 3 using the fluctuation dissipation theory. Non-classical (concentration dependent) rate constants ate found for the low dimensional systems (d= 1,2) when the bimolecular process dominates unimolecular decay.