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Non-classical free-radical polymerization: 7. Kinetic analysis of some polymerizations by the group-termination coefficient procedure

✍ Scribed by C.H. Bamford

Book ID
107846288
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
518 KB
Volume
31
Category
Article
ISSN
0032-3861

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πŸ“œ SIMILAR VOLUMES

Non-stationary states in free-radical po
Non-stationary states in free-radical polymerizations with size-dependent termination. Studies by the group-termination procedureβ€”3. Further consideration of after-and pre-effects and evaluation of absolute coefficients
✍ C.H. Bamford πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 486 KB

Al~traet--In earlier studies of the kinetic quantities in non-stationary stages of non-classical free-radical polymerization a relation between the total pre-and after-effects (AMos, AM~, respectively) and the rate coefficients kp kto was proposed. This arose from the results of numerical computatio

Non-stationary states in free-radical po
Non-stationary states in free-radical polymerizations with size-dependent termination. Studies by the group-termination procedureβ€”2. Pre-effects and systems with intermittent initiation
✍ C.H. Bamford πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 536 KB

Abstraet~Calculations on non-classical systems of the type mentioned in the title have been carried out 'iJsing the treatment described in Part I. As before chain transfer has been neglected. It is shown that the properties of the total pre-effect AMpr ~ are analogous to those previously deduced for