Noise-Free Determination of Isochromatic Parameter of Stereolithography-Built Models

Free-radical polymerization engineering—

Free-radical polymerization engineering—IV. Modelling homogeneous polymerization of ethylene: determination of model parameters and final adjustment of kinetic coefficients

✍ Pascal Lorenzini; Michel Pons; Jacques Villermaux 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 773 KB

A mathematical mode1 for free-radical polymerization of ethylene was established in a previous paper. The present paper deals with the determin ation of kinetic parameters of this mode1 by optimal fitting of experimental data obtained in a bench-scale CSTR. Overall polymerization rate coefficient an