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NO reduction with CO in the presence and absence of H2O over Pd/γ-Al2O3 and Pd-VOx/γ-Al2O3 catalysts: The formation of HNCO, NH3 and stable surface species

✍ Scribed by C. Neyertz; M. Volpe; D. Perez; I. Costilla; M. Sanchez; C. Gigola

Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
557 KB
Volume
368
Category
Article
ISSN
0926-860X

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The selective reduction of NO x with added oxygenates over BaNa/Y and Ag/Y zeolites and Ag/g-Al 2 O 3 takes place via complex reaction pathways with a number of common crucial intermediates. Acetate ions are formed by the oxidation of acetaldehyde over these catalysts. These acetate ions react with