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No lubricants from fluorinated C60

โœ Scribed by TAYLOR, ROGER; AVENT, ANTHONY G.; DENNIS, T. JOHN; HARE, JONATHON P.; KROTO, HAROLD W.; WALTON, DAVID R. M.; HOLLOWAY, JOHN H.; HOPE, ERIC G.; LANGLEY, G. JOHN


Book ID
109779214
Publisher
Nature Publishing Group
Year
1992
Tongue
English
Weight
272 KB
Volume
355
Category
Article
ISSN
0028-0836

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Nucleophilic substitution of fluorinated
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Exo-fluorinated C60F60 has Ih symmetry
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Contrary to a recent suggestion that externally fluorinated C&Fe0 may posses I rather than 1s symmetry, we report theoretical ab initio evidence favoring an Ih equilibrium structure. However, as with C60H60, we find that the lowest minimum structure contains fluorine atoms inside the Cso cage. ## T