N(nPr)4[B5O6(OH)4][B(OH)3]2and N(nBu)4[B5O6(OH)4][B(OH)3]2: Clathrates with a diamondoid arrangement of hydrogen-bonded pentaborate anions
✍ Scribed by Clemens C. Freyhardt; Michael Wiebcke; Jürgen Felsche; Günter Engelhardt
- Book ID
- 104897064
- Publisher
- Springer Netherlands
- Year
- 1994
- Tongue
- English
- Weight
- 762 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0923-0750
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Large single crystals of the polar, hydrated pentaborates Me[B 5 O 6 (OH) 4 ]•2H 2 O (Me = Rb, NH 4 ) were grown from aqueous solutions. The structure of NH 4 [B 5 O 6 (OH) 4 ]•2H 2 O was redetermined and proved to be orthorhombic (space group Aba2 (No. 41) with a = 11.3192(7) Å, b = 11.0261(8) Å, c
The crystal structure of synthetic Rb 2 [B 4 O 5 (OH) 4 ] ' 3.6H 2 O has been established from single-crystal X-ray di4raction data. It crystallizes in the orthorhombic space group Pbcn with a unit cell of dimensions a ؍ 11.276(5) A s , b ؍ 13.097(14) A s , c ؍ 16.751(5) A s ; V ؍ 2474(3) A