N,N,N′,N′-Tetraphenyl-1,1′-biphenyl-4,4′-diamine
✍ Scribed by Zhang, Hai-Guang ;Yu, Wen-Tao ;Yan, Shi-Na ;Cheng, Chao ;Tao, Xu-Tang
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 213 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The molecule of the title compound, C 36 H 28 N 2 , adopts a propeller-like shape and possesses crystallographically imposed twofold rotation symmetry. The N atom has an almost ideal trigonal geometry, indicating that the lone electron pair is involved in conjugation with the system of aromatic rings.
📜 SIMILAR VOLUMES
In the crystal structure of the title compound, C 18 H 14 N 4 , there are two independent centrosymmetric molecules with different conformations. The two molecules are linked to each other via weak C-HÁ Á ÁN hydrogen bonds and C-HÁ Á Á interactions.
The molecule of the title compound, C~22~H~30~N~4~, lies across a crystallographic inversion centre and adopts an __E__ configuration with respect to the azomethine C=N bond. The molecular structure has a staggered conformation, with the two benzene rings parallel to each other. The dihedral angle b