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N,N-Dialkylhydrazones as the Imine Component in the Staudinger-Like [2+2] Cycloaddition to Benzyloxyketene

✍ Scribed by Rosario Fernández; Ana Ferrete; José M. Lassaletta; José M. Llera; Eloísa Martín-Zamora

Book ID
101374720
Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
80 KB
Volume
114
Category
Article
ISSN
0044-8249

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Complete π-Facial Stereoselectivity in t
Complete π-Facial Stereoselectivity in the TiCl4-Mediated [4 + 2] Cycloaddition of Cyclopentadiene to N,N′-fumaroyldi[(2R)-bornane-10,2-sultam]
✍ Christian Chapius; Piotr Rzepecki; Tomasz Bauer; Janusz Jurczak 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 German ⚖ 417 KB

## Abstract Under the co‐operative influence of two prosthetic groups, and independent of the TiCl~4~ concentration, complete and constant diastereofacial π‐selection was achieved during the [4 + 2] cycloaddition of cyclopentadiene to __N__,__N__′‐fumaroyl‐di[(2__R__)‐bornane‐10,2‐sultam] ((−)‐1c);