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N,N′-Bis(trimethylsilylmethyl)thiocarbamide andN,N′-Bis(trimethylsilylmethyl)-λ6-thiocarbamideS,S-Dioxide

✍ Scribed by N. N. Vlasova; O. Yu. Grigor’eva; M. G. Voronkov


Book ID
106522790
Publisher
Springer
Year
2005
Tongue
English
Weight
36 KB
Volume
75
Category
Article
ISSN
1070-3632

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The rhodium(II)-catalyzed reaction of N-
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The N-bis(trimethysilyl)methyl (N-BTMSM) group is effective for conformational control about the amide N C(O) bond in tertiary diazoamides; metallocarbenoid C-H insertion reaction occurs only at the other N-'alkyl' unit. In C a -unbranched diazoamides, the inherent electronic effects of the N-'alkyl