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N,N-Bis(tert-butyldimethylsilyloxy)aminobenzene as a new synthetic equivalent of nitrosobenzene

✍ Scribed by A. D. Dilman; I. M. Lyapkalo; P. A. Belyakov; S. L. Ioffe; Yu. A. Strelenko; V. A. Tartakovsky


Book ID
105595645
Publisher
Springer
Year
2000
Tongue
English
Weight
101 KB
Volume
49
Category
Article
ISSN
1573-9171

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1-(N-Acylamino)alkyltriphenylphosphonium
✍ Roman Mazurkiewicz; Agnieszka PaΕΊdzierniok-Holewa; Beata OrliΕ„ska; Sebastian Ste πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 French βš– 276 KB

1-(N-Acylaminoalkyl)triphenylphosphonium salts 2a-f on reaction with DBU in MeCN are transformed into 1-(N-acylaminoalkyl)amidinium salts 3a-f. Amidinium salts 3d-f with a proton at the b-position undergo slow tautomerization into the corresponding enamides 6d-f. The same 1-(N-acylamino)alkyltriphen