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N,N′-Bis(4-chloro­benzyl­idene)propane-1,2-diamine

✍ Scribed by Yang, Shu-Ping ;Han, Li-Jun ;Wang, Da-Qi ;Xia, Hai-Tao

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
260 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C 17 H 16 Cl 2 N 2 , adopts a 'vault' conformation. The molecules are linked by a pair of C-HÁ Á ÁN hydrogen bonds into a centrosymmetric dimer with an R 2 2 (18) ring. These dimers are linked by a weak centrosymmetricinteraction into a chain along the [001] direction, and these chains are connected by van der Waals interactions, resulting in a three-dimensional network structure.

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In the title compound, [Cu(C 23 H 24 N 2 O 2 )], the Cu II atom is coordinated by two imine N and two phenol O atoms of the ligand. The geometry of the coordination is distorted tetrahedral. The dihedral angle between the N/Cu/O coordination planes is 7.37 (7) .