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N,N′-Bis[2-(2-pyrid­yl)eth­yl]dithio­oxamide

✍ Scribed by Cui, Jian-Zhong ;Zhang, Dan ;Pan, Shuo-Wen ;Cheng, Peng ;Liao, Dai-Zheng ;Wang, Geng-Lin

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
422 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C 16 H 18 N 4 S 2 , has a crystallographic inversion centre at the mid-point of the central C-C bond. The plane of the dithiooxamide fragment is approximately perpendicular to the plane of the dimethylene bridge [dihedral angle = 84.8 (1) ], the plane of which is in turn normal to the pyridine ring plane [dihedral angle = 89.80 (8) ]. An intermolecular N-HÁ Á ÁN hydrogen bond involving the amide NH group and the pyridine N atom [NÁ Á ÁN = 3.0503 (18) A ˚and N-HÁ Á ÁN = 145.8 ( 14) ] links the molecules into chains extending along the c axis.

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