NMR study of the structure and properties of poly(MMA-co-VP) crosslinked hydrogels
β Scribed by I. Calderara; R. Gougeon; L. Delmotte; V. Lemee; D. J. Lougnot
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 157 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0887-624X
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β¦ Synopsis
1 H-and 13 C-NMR techniques were used to study the microscopic structure of NMA/VP copolymer hydrogels. Evidence was obtained for a plasticization effect of MMA chains by VP. An original 1 H-NMR approach revealed the existence of several types of water with various degree of bounding to the polymer network, a conclusion that is corroborated by a complementary 13 C-NMR study.
π SIMILAR VOLUMES
Films were prepared by reaction of HEMA monomer with the crosslinking agent ethyleneglycol dimethacrylate (EGDMA) at crosslinking ratios, X, of 0.005, 0.01, 0.0128, 0.025, and 0.050 mol EGDMA/mol HEMA in the presence of 40 wt. % water at 60Β°C for 12 h. These membranes were subsequently swollen in wa
## Abstract Poly (acrylamideβ__co__βmethyl methacrylate) hydrogels of different ratios were prepared by using chemical and physical crosslinks to study the effect of nature of crosslinks on swelling behavior of hydrogels. The chemically crosslinked gels were prepared by using __NN__β²βmethylene bis