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NMR study of platinum microcrystals and application to thermometry

โœ Scribed by I. Yu; W.P. Halperin


Book ID
103808246
Publisher
Elsevier Science
Year
1981
Weight
166 KB
Volume
107
Category
Article
ISSN
0378-4363

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15N-NMR. and 31P-NMR. Studies of palladi
โœ Herbert Motschi; Paul S. Pregosin; Luigi M. Venanzi ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 561 KB

NH2(CH&CH3 and (for Pt) C2H4. For both metals, the NMR. parameters depend on the trans-influence of the ligand L. The values 1J(195Pt, 15N) vary from 138 to 336 Hz and can be shown to correlate with the values 1J(195Pt, 31P) in the complexes trans-[PtCl,(PBu!j)L]. There is a linear relation between