Bamers to rotation about the partial double C-N' bond were determined from line shape analysis of 'H and I3C dynamic NMR spectra of N',N'-dimethyl-NZ-substituted phenylacetamidines with twelve different substituents on the phenyl ring. The values of AGGc are 51.2-58.7 kJ mol-' and the correlation wi
NMR study of N1N1-dimethyl-N2-arylureas
โ Scribed by Iwona Wawer; Vera Koleva
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 320 KB
- Volume
- 344
- Category
- Article
- ISSN
- 0022-2860
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## Abstract ^13^C and ^15^N NMR chemical shifts were measured for __N__^1^โalkylโ__N__^2^โarylthioureas. The absence of decoalescence of the __N__^1^โalkyl group carbon signals down to 190 K, the europiumโinduced chemical shifts and the molecular mechanics calculations indicate that the preferred c