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NMR study of 4-deoxy-α-L-threo-4-enohexopyranosyluronic acid (1 → 3)2-acetamido-2-deoxy-D-hexoses produced in the enzymic digestion of hyaluronate, chondroitin and chondroitin sulfates

✍ Scribed by Shigehiro Hirano


Publisher
John Wiley and Sons
Year
1970
Tongue
English
Weight
201 KB
Volume
2
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

The conformation of 4‐deoxy‐α‐L‐threo‐4‐enohexopyranosyluronic acid (1 → 3)2‐acetamido‐2‐deoxy‐d‐hexoses was analyzed by NMR spectroscopy. The half‐chair (H~1~^2^) conformation was found in the unsaturated uronide moiety and the chair (Cl) conformation in the hexosamine moiety.