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NMR studies on the interaction of ethyl-aluminium chlorides with some methyl-substituted pyridines

✍ Scribed by Gen-Etsu Matsubayashi; Kizuku Wakatsuki; Toshio Tanaka

Publisher: John Wiley and Sons
Year: 1971
Tongue: English
Weight: 424 KB
Volume: 3
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270030609

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✦ Synopsis

The interaction of triethylaluminium, diethylaluminium chloride and ethylaluminium dichloride with some methyl-substituted pyridines has been investigated in 1,2-dichloroethane or dichloromethane by means of NMR spectroscopy. 2,6-Dimethyl-and 2,4,6-trimethyl-pyridine have been found to form three types of complexes with diethylaluminium chloride and ethylaluminium dichloride in solution. In addition, the configurations of the complexes in solution have been estimated from proton NMR chemical shifts of the methyl-substituted pyridines and the conductivity measurements.

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