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NMR studies of the dynamic behavior of 2-anilino-6-chloro-4-methoxy-1,3,5-triazine in solution

✍ Scribed by P. A. Belyakov; A. V. Shastin; Yu. A. Strelenko


Book ID
110333451
Publisher
Springer
Year
2001
Tongue
English
Weight
239 KB
Volume
50
Category
Article
ISSN
1573-9171

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The energy for breaking the intramolecular hydrogen bond between the phenolic OH and an aza nitrogen in two 2,4-diaryl-6-(2-hydroxy-4-methoxyphenyl)-1,3,5-triazines was determined, by dynamic 1H and 13C NMR spectroscopy, as 55 Β» 5 kJ mol-1. The activation parameters DHt and DSt for the corresponding