Studies in nickel(IV) chemistry. Kinetic
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G. Neogi; S. Acharya; R. K. Panda; D. Ramaswamy
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Article
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1983
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John Wiley and Sons
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English
β 688 KB
Kinetics of the Cu(I1) ion-mediated acid decomposition of tris(dimethylg1yoximato)nickelate(IV), Ni(dmg);-(dmg2-= dimethylglyoximate dianion), are reported in aqueous medium in the range of 3.6 < pH < 6.6 a t 35OC and p = 0.57M. The pseudo-first-order rate constants of the disappearance of Ni(1V) (h