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NMR studies of nickel hydrides: the intramolecular rearrangement of the hydridotris(tri-p-tolyl phosphite)nickel(II) ion

✍ Scribed by Eaton, Donald R.; McGlinchey, Michael J.; Moffat, Karen A.; Buist, Richard J.


Book ID
126835565
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
830 KB
Volume
106
Category
Article
ISSN
0002-7863

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Studies in nickel(IV) chemistry. Kinetic
✍ G. Neogi; S. Acharya; R. K. Panda; D. Ramaswamy πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 English βš– 688 KB

Kinetics of the Cu(I1) ion-mediated acid decomposition of tris(dimethylg1yoximato)nickelate(IV), Ni(dmg);-(dmg2-= dimethylglyoximate dianion), are reported in aqueous medium in the range of 3.6 < pH < 6.6 a t 35OC and p = 0.57M. The pseudo-first-order rate constants of the disappearance of Ni(1V) (h